From RepRap web site:
PID tuning refers to the parameters' adjustment of a proportional-integral-derivative control algorithm used in most repraps for hot ends and heated beds.
Note: Contrary to previous versions of ADVi3++, you can only perform the PID tuning god the extruder, not if the bed. PID tuning of the bed is not so important and the removale of this feature gives more memory (SRAM) for other features. For the same reason, there is only one set of PID values recorded.